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Recent progress in the Valley Hall insulator has demonstrated a nontrivial topology property due to the distinct valley index in 2D semiconductor systems. In this work, we propose a highly tunable topological phase transition based on valley photonic crystals. The topological phase transition is realized by the inversion symmetry broken due to the refractive index change of structures consisting of optical phase change material (OPCM) with thermal excitation of different sites in a honeycomb lattice structure. Besides, simulations of light propagation at sharp corners and pseudo-spin photon coupling are conducted to quantitatively examine the topological protection. Compared with other electro-optical materials based on reconfigurable topological photonics, a wider bandwidth and greater tunability of both central bandgap frequency and topological phase transition can happen in the proposed scheme. Our platform has great potential in practical applications in lasing, light sensing, and high-contrast tunable optical filters.

 

The green leaf volatiles (GLVs)Z‐3‐hexen‐1‐ol (Z3‐HOL) andZ‐3‐hexenyl acetate (Z3‐HAC) are airborne infochemicals released from damaged plant tissues that induce defenses and developmental responses in receiver plants, but little is known about their mechanism of action. We found that Z3‐HOL and Z3‐HAC induce similar but distinctive physiological and signaling responses in tomato seedlings and cell cultures. In seedlings, Z3‐HAC showed a stronger root growth inhibition effect than Z3‐HOL. In cell cultures, the two GLVs induced distinct changes in MAP kinase (MAPK) activity and proton fluxes as well as rapid and massive changes in the phosphorylation status of proteins within 5 min. Many of these phosphoproteins are involved in reprogramming the proteome from cellular homoeostasis to stress and include pattern recognition receptors, a receptor‐like cytoplasmic kinase, MAPK cascade components, calcium signaling proteins and transcriptional regulators. These are well‐known components of damage‐associated molecular pattern (DAMP) signaling pathways. These rapid changes in the phosphoproteome may underly the activation of defense and developmental responses to GLVs. Our data provide further evidence that GLVs function like DAMPs and indicate that GLVs coopt DAMP signaling pathways.

 

Arctic Ocean gateway fluxes play a crucial role in linking the Arctic with the global ocean and affecting climate and marine ecosystems. We reviewed past studies on Arctic–Subarctic ocean linkages and examined their changes and driving mechanisms. Our review highlights that radical changes occurred in the inflows and outflows of the Arctic Ocean during the 2010s. Specifically, the Pacific inflow temperature in the Bering Strait and Atlantic inflow temperature in the Fram Strait hit record highs, while the Pacific inflow salinity in the Bering Strait and Arctic outflow salinity in the Davis and Fram straits hit record lows. Both the ocean heat convergence from lower latitudes to the Arctic and the hydrological cycle connecting the Arctic with Subarctic seas were stronger in 2000–2020 than in 1980–2000. CMIP6 models project a continuing increase in poleward ocean heat convergence in the 21st century, mainly due to warming of inflow waters. They also predict an increase in freshwater input to the Arctic Ocean, with the largest increase in freshwater export expected to occur in the Fram Strait due to both increased ocean volume export and decreased salinity. Fram Strait sea ice volume export hit a record low in the 2010s and is projected to continue to decrease along with Arctic sea ice decline. We quantitatively attribute the variability of the volume, heat, and freshwater transports in the Arctic gateways to forcing within and outside the Arctic based on dedicated numerical simulations and emphasize the importance of both origins in driving the variability. 

The interrelation is explored between external pressure (0.1, 1, and 10 MPa), solid electrolyte interphase (SEI) structure/morphology, and lithium metal plating/stripping behavior. To simulate anode‐free lithium metal batteries (AF‐LMBs) analysis is performed on “empty” Cu current collectors in standard carbonate electrolyte. Lower pressure promotes organic‐rich SEI and macroscopically heterogeneous, filament‐like Li electrodeposits interspersed with pores. Higher pressure promotes inorganic F‐rich SEI with more uniform and denser Li film. A “seeding layer” of lithiated pristine graphene (pG@Cu) favors an anion‐derived F‐rich SEI and promotes uniform metal electrodeposition, enabling extended electrochemical stability at a lower pressure. State‐of‐the‐art electrochemical performance is achieved at 1MPa: pG‐enabled half‐cell is stable after 300 h (50 cycles) at 1 mA cm⁻²rate −3 mAh cm⁻²capacity (17.5 µm plated/stripped), with cycling Coulombic efficiency (CE) of 99.8%. AF‐LMB cells with high mass loading NMC622 cathode (21 mg cm⁻²) undergo 200 cycles with a CE of 99.4% at C/5‐charge and C/2‐discharge (1C = 178 mAh g⁻¹). Density functional theory (DFT) highlights the differences in the adsorption energy of solvated‐Li⁺onto various crystal planes of Cu (100), (110), and (111), versus lithiated/delithiated (0001) graphene, giving insight regarding the role of support surface energetics in promoting SEI heterogeneity.

 

Mesoscale eddies are important to many aspects of the dynamics of the Arctic Ocean. Among others, they maintain the halocline and interact with the Atlantic Water circumpolar boundary current through lateral eddy fluxes and shelf-basin exchanges. Mesoscale eddies are also important for transporting biological material and for modifying sea ice distribution. Here, we review what is known about eddies and their impacts in the Arctic Ocean in the context of rapid climate change. Eddy kinetic energy (EKE) is a proxy for mesoscale variability in the ocean due to eddies. We present the first quantification of EKE from moored observations across the entire Arctic Ocean and compare those results to output from an eddy resolving numerical model. We show that EKE is largest in the northern Nordic Seas/Fram Strait and it is also elevated along the shelf break of the Arctic Circumpolar Boundary Current, especially in the Beaufort Sea. In the central basins, EKE is 100–1,000 times lower. Generally, EKE is stronger when sea ice concentration is low versus times of dense ice cover. As sea ice declines, we anticipate that areas in the Arctic Ocean where conditions typical of the North Atlantic and North Pacific prevail will increase. We conclude that the future Arctic Ocean will feature more energetic mesoscale variability.